A perfume composition for expressing fragrance of white maehwa(Prunus mume Sieb. et Zucc.) is provided to realize the unique fragrance of the white maewha and to obtain a skin therapeutic agent. A perfume composition for expressing fragrance of white maehwa(Prunus mume Sieb. et Zucc.) is characterized by containing fragrance component of white maehwa and florol that are analyzed by an SPME method as effective ingredients. The fragrance components of the white maehwa are Benzaldehyde, Benzyl acetate and Benzyl alcohol. The fragrance components of the white maehwa further contains AcetophenoneDecanalNonanal, 2,2,6-trimethyl-5-cyclohexene-1,4-dione, Iso-Butylalcohol, DodecaneEugenol, CamphorTridecane and Hexanal.본 발명에 따른 조성물은 SPME법에 의해 백매화의 향취성분으로서 분석된 벤즈알데하이드 (Benzaldehyde), 벤질 아세테이트 (Benzyl acetate)와 벤질 알코올 (Benzyl alcohol) 등에, 깨끗한 꽃 향취를 가진 인공 합성 물질인 플로롤 (Florol)을 함유한 것으로서, 야생 백매화의 고유 향취를 재현하면서 뛰어난 기호성을 갖는 향료 조성물에 관한 것이다.