Disclosed are compositions comprising (a) at least one compound selected from compounds of Formula1,N-oxides, and salt thereof,wherein R1is phenyl optionally substituted with up to 5 substituents independently selected from R3, or pyridinyl optionally substituted with up to 4 substituents independently selected from R3； R2is C1-C4haloalkyl； or thiazolyl, pyridinyl or pyrimidinyl, each optionally substituted with up to 2 substituents independently selected from the group consisting of halogen and C1-C4alkyl； each R3is independently halogen, cyano, C1-C4alkyl, C1-C4haloalkyl, C1-C4alkoxy, C1-C4haloalkoxy, C(R4)=NOR4or Q； each R4is independently C1-C4alkyl； Z is CH=CH or S； and each Q is independently phenyl or pyridinyl, each optionally substituted with up to 3 substituents independently selected from the group consisting of halogen, cyano, C1-C4alkyl, C1-C4haloalkyl, C1-C4alkoxy and C1-C4haloalkoxy； and (b) at least one invertebrate pest control agent.Also disclosed are methods for controlling an invertebrate pest comprising contacting the invertebrate pest or its environment with a biologically effective amount of a composition of the invention.本發明揭露之組合物包含(a)至少一化合物，選自式1化合物、其N-氧化物及其鹽類，其中R1係視情況以至多5個分別選自R3的取代基所取代的苯基，或視情況以至多4個分別選自R3的取代基所取代的吡啶基；R2為C1-C4鹵烷基；或噻唑基、吡啶基或嘧啶基，各視情況以至多2個分別選自於由鹵素及C1-C4烷基所組成的群組之取代基所取代；各R3分別為鹵素、氰基、C1-C4烷基、C1-C4鹵烷基、C1-C4烷氧基、C1-C4鹵烷氧基、C(R4)=NOR4或Q；各R4分別為C1-C4烷基；Z為CH=CH或S；以及各Q分別為苯基或吡啶基，各視情況以至多3個分別選自於由鹵素、氰基、C1-C4烷基、C1-C4鹵烷基、C1-C4烷氧基及C1-C4鹵烷氧基所組成的群組之取代基所取代；以及(b)至少一無脊椎動物害蟲控制劑。本發明亦揭露控制一無脊椎動物害蟲的方法，包含以本發明之生物有效量組合物接觸該無脊椎動物害蟲或其環境。
