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Ionic liquids with ascorbate anion, method for obtaining them and their application as feeding deterrents
专利权人:
INSTYTUT OCHRONY ROŚLIN - PAŃSTWOWY INSTYTUT BADAWCZY W POZNANIU
发明人:
JULIUSZ PERNAK,TOMASZ KLEJDYSZ,KACPER KOTERAS,MICHAŁ NIEMCZAK
申请号:
PL420726
公开号:
PL233922B1
申请日:
2017.03.03
申请国别(地区):
PL
年份:
2019
代理人:
摘要:
the subject of ion liquids are of anionem askorbinianowym and kationem amoniowym, of the general formula 1.in which k means cation: dicocodimetyloamoniowy of general formula (2) or (hydrogenated tallow) of benzyldimethyl ammonium general formula 3, or bis (hydroxyethyl) metylooleylamoniowy of general formula 4.or didecylodimetylo ammonium of general formula 5, or dimetylodioktyloamoniowy, or tetradecylotrimetyloamoniowy, or heksadecylotrimetyloamoniowy, or oktadecylotrimetyloamoniowy,docosyltrimethylammonium or where 'coco' means saturated alkyl substituent of eight (5%), 10 (6%), 12 (50%), 14 (19%).sixteen (10%) and 18 (10%) carbon atoms; hydrogenated tallow 'means saturated alkyl substituent of 12 (1%), 14 (4%).16 (31%) and 18 (64%) carbon atoms; "oleyl " means the insatiable substituent alkyl of 12 (5%), 14 (1%), 16 (14%) and 18 (18%) carbon atoms.the application also includes a method for receiving, that is,the corresponding quaternary ammonium chloride is subjected to the reaction of nitrate with potassium hydroxide in a mole ratio of 1: 1, in an organic solvent with the group: isopropanol or acetonitrile.or methanol or acetone or ethanol, preferably methanol, at a temperature of from 20 to 60 u00b0c, preferably 105, after which the separated product of ods u0105cza,quaternary ammonium hydroxide and the remaining in the filtrate is subjected to reaction inerting with ascorbic acid in a mole ratio of 1: 1, at a temperature of from 20 to 100 degrees, beneficial use.at the time of at least 10 minutes, and then vaporized solvents and the product dried under reduced pressure.object of the application is also applicable to ionic liquids anionem askorbinianowym as deterenty poisoning ionic liquids.
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