Provided is a reduced coenzyme Q10 composition that is suitable for inexpensive and simple formulation that can meet the demands of the market, that has good oxidation stability, and that is a solid at room temperature. More specifically, the composition is a solid at 25 DEG C and comprises reduced coenzyme Q10, an organic acid, and a carbonate that contains sodium cations and/or calcium cations. The organic acid is preferably itaconic acid, L-ascorbic acid, tartaric acid, citric acid, or erythorbic acid. The carbonate is preferably sodium carbonate, sodium hydrogen carbonate, calcium carbonate, or a hydrate thereof.本發明提供一種適合於可因應市場需求之廉價且簡便之製劑化、氧化穩定性良好、室溫下為固體狀態之還原型輔酶Q10組合物,詳細而言,本發明提供一種含有還原型輔酶Q10、有機酸、以及包含鈉陽離子及/或鈣陽離子之碳酸鹽且25℃下為固體狀態之組合物。作為有機酸,較佳為伊康酸、L-抗壞血酸、酒石酸、檸檬酸或異抗壞血酸,作為碳酸鹽,較佳為碳酸鈉、碳酸氫鈉、碳酸鈣或其等之水合物。