The invention relates to a composition comprising: (i) a trialkylsiloxysilylcarbamoyl pullulan compound, (ii) a polymethylmethacrylate polymer, (iii) a matting material, and (iv) at least one volatile hydrocarbon oil. The invention is also directed to the use of such a composition for making up and/or caring for keratin materials, the skin and the lips, and more particularly in mascaras, foundations and lipsticks.