PROBLEM TO BE SOLVED: To provide an analyzing method for high-boiling point compound in tar, allowing even a high-boiling point component in tar to be accurately analyzed. SOLUTION: This analyzing method and a GC(Gas Chromatography) analyzing instrument for high-boiling point compound in tar are characterized in that organic-solvent insoluble portions are removed from the tar by using an organic solvent, and organic-solvent soluble portions are GC-analyzed.