On a substrate 2 made of copper or a copper alloy, a zinc-nickel alloy layer 4 containing zinc and nickel, and a tin layer 5 made of a tin alloy are laminated in this order, wherein the zinc-nickel alloy layer 4 has a thickness of 0.1-5 µm and has a nickel content of 5-50 mass%, the tin layer 5 has a zinc concentration of 0.6-15 mass%, and, under an oxide layer 6 which is the outermost layer, a metal zinc layer 7, having a zinc concentration of 5-40 at% and a thickness of 1-10 nm in terms of SiO2, is formed on the tin layer 5.