An extra fine multifilament obtained in the present invention contains a deodorant functional agent having a particle diameter equal to or more than the average diameter of extra fine single yarn fibers, and the deodorant functional agent is not completely covered with polymer and is partially exposed on the surface of the multifilament, whereby a dramatically improved deodorizing function can be achieved. Accordingly, a polyester cloth made of the multifilament has a durable deodorizing function, a high strength, and an excellent texture, and thereby is useful for apparel products (such as sports wears, casual wears, and mens and womens suits) , medical applications, interior applications, etc.