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SOLID-STATE CRYSTALLIZATION OF METAL ORGANIC FRAMEWORKS WITHIN MESOPOROUS METERIALS METHODS AND HYBRID MATERIALS THEREOF
专利权人:
RESEARCH TRIANGLE INSTITUTE
发明人:
LUZ MINGUEZ, Ignacio,SOUKRI, Mustapha,LAIL, Marty
申请号:
WO2017US46231
公开号:
WO2018031733(A1)
申请日:
2017.08.10
申请国别(地区):
世界知识产权组织国际局
年份:
2018
代理人:
摘要:
A method, comprising i) contacting an aqueous solution of an organic ligand salt of the formula AX(L-X) with a mesoporous material (MPM) to form an impregnated mesoporous salt material of the formula AX(L-X)/MPM, ii) treating the impregnated mesoporous salt material with an aqueous acidic solution to form an impregnated mesoporous acid material of the formula HX(L-X)/MPM, iii) contacting an aqueous solution of a metal precursor of the formula M+y(B)y with the impregnated mesoporous acid material to form an impregnated mesoporous metal organic framework precursor of the formula [M+y(B)y][Hx(L-x)]/MPM, and iv) at least one of 1) heating the impregnated mesoporous metal organic framework precursor in the absence of a solvent or 2) exposing the impregnated mesoporous metal organic framework precursor to a volatile vapor in the absence of a solvent such that the heating or the exposing forms a hybrid material of the formula (M+yL-x)/MPM, wherein the hybrid material comprises a nano-crystalline metal organic framew
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