The present invention relates to technological improvement in an electrostatic spraying method for skin, and more specifically, to an increase in the adhesion of a coating film formed on the skin by electrostatic spraying. Provided is a method for producing a coating film on skin, the method being characterized by having, in the following order or reverse order: a liquid agent application step for applying a polymer-containing liquid agent onto the skin by a method other than electrostatic spraying and a step for electrostatically spraying a composition containing component (a) and component (b) onto the skin directly to form a coating film on the skin. Component (a) is a volatile substance of at least one selected from the group consisting of water, alcohol, and ketone and component (b) is a polymer having an ability to form a coating film.本發明係對皮膚之靜電噴塗法之技術的提升,更詳言之,係提高藉靜電噴塗而形成於皮膚之覆膜之密黏性。本發明係於皮膚上之覆膜之製造方法,其特徵為依下述順序或相反順序具有:將含有聚合物之液劑藉由靜電噴塗以外之方法施用至皮膚的液劑應用步驟;與將含有成分(a)及成分(b)之組成物直接靜電噴塗至皮膚而於皮膚上形成覆膜的步驟。(a)選自水、醇類及酮類之1種或2種以上之揮發性物質;(b)具有覆膜形成能力之聚合物。
