Provided is a coating film having a uniform and strong ultraviolet protection effect on the whole skin. Also provided is a method for producing an ultraviolet protection coating film on skin, the method being characterized by having, in the following order or reverse order: a step for applying an ultraviolet protection agent-containing composition onto the skin; and a step for electrostatically spraying a composition containing component (a) and component (b) onto the skin directly to form a coating film on the skin. Component (a) is a volatile substance of at least one selected from among water, alcohol, and ketone; and component (b) is a polymer having an ability to form a coating film.本發明係提供一種於皮膚全體具有均勻且強力之紫外線防禦效果的覆膜。本發明係於皮膚上之紫外線防禦覆膜之製造方法,其特徵為依下述順序或相反順序具有:將含有紫外線防禦劑組成物塗佈至皮膚的步驟;與將含有成分(a)及成分(b)之組成物直接靜電噴塗至皮膚而於皮膚上形成覆膜的步驟;(a)選自水、醇類及酮類之1種或2種以上之揮發性物質;(b)具有覆膜形成能力之聚合物。