Provided is a method for producing a coating film having excellent adhesiveness to skin and excellent transparency by electrostatic spraying. A method for producing a coating film on skin, the method being characterized in that a composition including component (a), component (b), and component (c) is applied directly to skin by electrostatic spraying. (a) One or more volatile substances selected from alcohols and ketones, (b) a water-insoluble polymer having a coating film formation capability, and (c) an adhesive polymer other than component (b).本發明係提供一種藉由靜電噴塗法製造與皮膚之密黏性及透明性良好之覆膜的方法。本發明之於皮膚上之覆膜之製造方法,其特徵在於,將含有成分(a)、成分(b)及成分(c)之組成物直接對皮膚進行靜電噴塗。(a)選自醇類及酮類之1種或2種以上之揮發性物質。(b)具有覆膜形成能力之水不溶性聚合物。(c)成分(b)以外之黏著性聚合物。