PROBLEM TO BE SOLVED: To provide a hair shampoo which is good at foaming and good at eliminating foams at the time of rinse, grows the hair thick, and increases volume of the hair after drying.SOLUTION: A hair shampoo contains each component of the following (A)-(D). The amount of C12 free fatty acids and the amount of C14 free fatty acids which are comprised in an anionic surfactant (A) consisting of the following N-mixing fatty-acids (C12, C14) acyl monosodium L-aspartate liquid is respectively in the range of 15.5-19.5 mass% and 8.5-12.5 mass%. (A) 0.1-50 mass% of an anionic surfactant consisting of N-mixing fatty-acids (C12, C14) acyl monosodium L-aspartate liquid (B) 0.1-50 mass% of an ampholytic surfactant (C) 0.1-50 mass% of a nonionic surfactant (D) 0.01-2 mass% of an acrylic-acids polymer.COPYRIGHT: (C)2015,JPO&INPIT【課題】泡立ちが良好であり、すすぎの際の泡切れが良好であり、毛髪を太くし、乾燥後の毛髪のボリューム感が向上する毛髪洗浄料を提供すること。【解決手段】下記(A)~(D)の各成分を含有し、下記N-混合脂肪酸(C12,C14)アシル-L-アスパラギン酸ナトリウム液からなるアニオン性界面活性剤(A)に含まれるC12遊離脂肪酸量およびC14遊離脂肪酸量が、それぞれ15.5~19.5質量%および8.5~12.5質量%の範囲であることを特徴とする、毛髪洗浄料。(A)N-混合脂肪酸(C12,C14)アシル-L-アスパラギン酸ナトリウム液からなるアニオン性界面活性剤を0.1~50質量%(B)両性界面活性剤を0.1~50質量%(C)非イオン界面活性剤を0.1~50質量%(D)アクリル酸類高分子を0.01~2質量%【選択図】なし