The invention provides a crystalline 1,2-ethanedisulfonic acid salt of biphenyl-2-ylcarbamic acid 1-[2-(2-chloro-4-{[(R)-2-hydroxy-2-(8-hydroxy-2-oxo-1,2-dihydroquinolin-5-yl)ethylamino]methyl}-5-methoxyphenylcarbamoyl)ethyl]piperidin-4-yl ester or a solvate thereof. This invention also provides pharmaceutical compositions comprising such a salt or prepared using such a salt; processes and intermediates for preparing such a salt; and methods of using such a salt to treat a pulmonary disorder.本發明提供一種聯苯-2-基胺基甲酸1-[2-(2-氯-4-{[(R)-2-羥基-2-(8-羥基-2-氧代-1,2-二氫喹啉-5-基)乙基胺基]甲基}-5-甲氧基苯基胺基甲醯基)乙基]哌啶-4-酯或其溶劑化物之結晶1,2-乙烷二磺酸鹽。本發明亦提供包括該鹽或使用該鹽製備之醫藥組合物;製備該鹽之方法或中間物;及使用該鹽治療肺部疾病之方法。