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Systems and methods for separating chlorine-containing species from aqueous solutions of chlorine-containing species
专利权人:
UOP LLC
发明人:
Moser Mark D.,Wegerer David A.
申请号:
US201314062696
公开号:
US9718047(B2)
申请日:
2013.10.24
申请国别(地区):
美国
年份:
2017
代理人:
摘要:
Disclosed is a method for separating a chlorine-containing species from an aqueous solution of the chlorine-containing species in a catalytic hydrocarbon conversion process that includes the step of oxidizing a spent chloride-containing hydrocarbon conversion catalyst, the spent hydrocarbon conversion catalyst including a hydrocarbon residue formed thereon. The oxidizing forms a flue gas including chlorine-containing species, water, and oxides of carbon. The method further includes contacting the flue gas with a water scrubbing stream to dissolve at least a portion of the chlorine-containing species in the water scrubbing stream to form an aqueous acid solution and contacting the aqueous acid solution with a hygroscopic liquid to generate dehydrated hydrogen chloride gas. Still further, the method includes contacting the dehydrated hydrogen chloride gas with additional spent chloride-containing hydrocarbon conversion catalyst to sorb chlorine onto the additional spent chloride-containing hydrocarbon conversio
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