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PREPARING LONG CHAIN CARBOXYLIC ACIDS AND ALCOHOLS
专利权人:
BIOCHEMICAL RESEARCH CORP.
发明人:
ANDREW J. WELEBIR
申请号:
AU19790050438D
公开号:
AU5043879(A)
申请日:
1979.08.30
申请国别(地区):
澳大利亚
年份:
1980
代理人:
摘要:
A process for the preparation of long-chain carbon compounds comprises: a. reacting a carboxylic acid having 21 to 30 carbon atoms with a chlorinating agent to form the acid chloride; b. separating the acid chloride and reacting it with an enamine (e.g. 1- morpholino-cyclohexene) and a hindered tertiary amine in an organic solvent while maintaining the reaction temperature at 30 DEG to 60 DEG C; c. removing the solvent and recovering the beta-diketone product; d. reacting the beta-diketone with a solution of an alkali metal hydroxide or alkoxide and an alcohol; and e. recovering the precipitated product, the salt of a ketocarboxylic acid. The salt may be converted to the free acid, which may be reduced to the corresponding aliphatic acid and alcohol. A plant growth regulator composition comprises a substantially water-soluble solution of 1-triacontanol dissolved in a polar organic solvent, said polar organic solvent being present in an amount sufficient to render said concentrate water-soluble.
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