Provide novel structured compositions and the food comprising these compositions. The composition includes monoglyceride and two glyceride mixtures, and has high-caliber β crystal and small average grain size. They can be added in intermediate food, such as butter and margarine, then can be used to make final food, such as cake (such as: cake). Puffed pastry, Denmarks cake, baked donut, dough (for example, biscuit, piecrust), simulation cheese, frosting, freezing potato (for example, French fried potatoes) and/or other need fatty to provide the food of structure. Advantageously, the composition is originally used for providing the unhealthy fat of the structure in same food item by replacement, provides structure for ultimate food.