An assistance system for taking medicine includes at least one pill container, a processing module and an image capturing module. The pill container is used for containing a first medicine and has a first barcode corresponding to the first medicine. The image capturing module is coupled to the processing module and used to capture an image. The first barcode is in the image. The processing module assists a person who needs to take medicine according to the information of the first barcode.一種輔助用藥者服藥之系統,包括至少一藥物容器、一處理模組以及一影像擷取模組。藥物容器用於容置第一藥物,且具有對應第一藥物之一第一條碼。影像擷取模組耦接處理模組,影像擷取模組擷取一影像,影像具有第一條碼,處理模組依據第一條碼所載的一資料輔助一用藥者用藥。