Novel crystalline Forms of trisodium [3 ((1S 3R) l biphenyl 4 ylmethyl 3 ethoxycarbonyl 1 butyl carbamoyl) propionate (S) 3 methyl 2 (pentanoyl{2 (tetrazol 5 ylate)biphenyl 4 ylmethyl}amino)butyrate] hydrate methods for their preparation pharmaceutical compositions comprising these new forms and use of them for treating or delaying progression or onset of diseases or disorders related to activity of angiotensin receptor 1 (AT1) blockage and neprilysin (NEP) inhibition such as heart failure are disclosed.