The invention related to a one-pot process of making a single-phase silicone-acrylic hybrid adhesive composition comprising acrylic polymer and silicone polymer that are covalently bonded through a -Si-O-Si- linkage. The acrylic polymer contains at least one hydrolyzable silane (meth)acrylic monomer or siloxane (meth)acrylic macromer. These functional moieties provide reaction sites to form -Si-O-Si- bond by reacting hydrolyzable groups in the silicone polymer in the presence of a base or acid catalyst and water. The formed covalent bonds between the two incompatible systems of silicone polymer and acrylic polymer prevents phase separation and thereby a permanent, homogeneous single-phase system is formed.本發明係關於一種製造單相聚矽氧-丙烯酸混合型黏著劑組合物之一鍋製程，該組合物包含經由-Si-O-Si-鍵共價地鍵結之丙烯酸聚合物及聚矽氧聚合物。該丙烯酸聚合物含有至少一種可水解矽烷(甲基)丙烯酸單體或矽氧烷(甲基)丙烯酸大分子單體。此等官能性部分提供反應位點以藉由使該聚矽氧聚合物中之可水解基團在鹼或酸催化劑及水存在下反應來形成-Si-O-Si-鍵。在聚矽氧聚合物與丙烯酸聚合物之兩個不相容系統之間形成之共價鍵防止相分離，且從而形成永久性均質單相系統。
