HENNING, STEVEN K.,翰宁 史蒂芬Ｋ,翰寧 史蒂芬Ｋ,YOO, TAEJUN,柳泰俊,CHAO, HERBERT S.,赵 心一,趙 心一,翰宁 史蒂芬K,翰寧 史蒂芬K,赵 心一,趙 心一
申请号：
TW106131609
公开号：
TW201829495A
申请日:
2017.09.14
申请国别(地区):
TW
年份:
2018
代理人:
摘要：
A macromonomer precursor is provided that includes a polymeric chain derived from farnesene and a single functional terminal end. The functional terminal end may include a hydroxyl group, an amino group, an epoxy group, an isocyanato group, or a carboxylic acid group. The terminal end of the macromonomer precursor may then be reacted with a (meth)acrylate to form a macromonomer having a (meth)acrylate functionalized terminal end that may be (co)polymerized with radically polymerizable monomers, such as alkyl(meth)acrylate monomers. Alternatively, a copolymer may be obtained by first deriving a poly(meth)acrylate from (meth)acrylate monomers having reactive groups that would allow the macromonomer precursors to be grafted onto the poly(meth)acrylate in a second step. The resulting copolymer may be incorporated as an additive in various formulations, such as a lubricant, a hydraulic fluid, a cosmetic composition, and an adhesive composition.本文提供一種大分子單體前體，其包括衍生自金合歡烯之聚合鏈及單一官能末端。該官能末端可包括羥基、胺基、環氧基、異氰酸基或羧酸基團。然後可使該大分子單體前體之該末端與(甲基)丙烯酸酯反應，以形成具有 (甲基)丙烯酸酯官能化末端之大分子單體，其可與諸如(甲基)丙烯酸烷基酯單體之自由基可聚合單體(共)聚合。或者，共聚物可藉由首先自具有反應性基團之(甲基)丙烯酸酯單體衍生聚(甲基)丙烯酸酯獲得，該等反應性基團將容許在第二步驟中將該等大分子單體前體接枝至該聚(甲基)丙烯酸酯上。所得共聚物可作為添加劑納入多種調配物中，例如潤滑劑、液壓流體、化妝品組合物及黏著劑組合物。
