The present invention provides an atomizing method having an authentication mechanism, including the following steps: placing an atomized medicine contained in at least one atomized medicine container into an accommodating portion of an atomizing device; configuring an authentication module of an atomizing device to perform an authentication operation related to the authentication code carrier associated with the at least one atomized medicine container to determine the authenticity of the at least one atomized medicine container, and generate the authentication result signal correspondingly; and configuring the control unit of the atomization device to determine to determine whether to control the first power module connected to the atomization module to output a first driving voltage according to the authentication result signal.