A roof cover board made from a mixture of 30-60% stucco; 20-50% perlite; 10-30% cellulose fiber; 3-20% starch; and siloxane. Also disclosed is a stucco-free roof cover board made from a mixture of 30-60% perlite, 30-60% cellulose fiber, 5-25% starch; and siloxane. Also disclosed are methods for making same.