Via the novel steviol glycoside compound of No. 13 carbon (C13) connection of the non-saccharide portions point of stevioside it is characterized in that the remaining one second group of description of two or three glucopyranose that remaining one first group of the sum of tetrapyran glucose is connected via No. 19 carbon (C19) of the non-saccharide portions point of stevioside, is illustrated by compound 1-4. These compounds, which can be, to be present in a composition in the case where other steviol glycosides (for example, Mr. D and Mr. M) improve their solubility. Therefore, novel compounds can be in order to the preparation of the Aquo-composition of the higher concentration with steviol glycoside. A steviol glycoside composition including one or more of compound 1-4 is used as a sweetener composition to mitigate other compositions the constituent of sweetening (can), such as food, beverage, medicine, oral hygiene composition, nutraceutical etc..