The present invention discloses a microcapsule encapsulating a solid sunscreen and preparation and use thereof. The microcapsule comprises the solid sunscreen and a natural polymer. The solid sunscreen is encapsulated in a microcapsule formed of the natural polymer, wherein the solid sunscreen is an inorganic ultraviolet screening agent, an organic ultraviolet absorbent, or a mixture thereof. The natural polymer is agar, agarose, cellulose, chitosan, or a derivative thereof. The microcapsule of the present invention is useful in cosmetics, effectively prevents the solid sunscreen from decomposition, and reduces skin irritation as a result of the separation of the solid sunscreen from the skin. The natural polymer with hydrophilicity can cover blemish, improve skin feeling, and enhances the compatibility in the cosmetics.本發明公開了一種包裹固體防曬劑的微膠囊、製備方法及其應用。該微膠囊包含固體防曬劑和天然聚合物,該固體防曬劑包裹在該天然聚合物形成的微囊中,其中,該固體防曬劑是無機紫外遮蔽劑、有機紫外吸收劑或其混合物;該天然聚合物為瓊脂、瓊脂糖、纖維素、幾丁聚糖或其衍生物。本發明的微膠囊可用於化妝品中,有效避免固體防曬劑的分解,且將固體防曬劑與皮膚分隔開,減小對皮膚的刺激,親水的天然聚合物可遮蓋顏色、改善手感、增強其在化妝品中的配合性。