A hair cleansing composition containing micro emulsion with excellent stability is provided to show high conditioning effect and ensure stability at low and high temperatures by containing the large amount of hair care oily ingredients. A hair cleansing composition containing micro emulsion with excellent stability comprises anionic surfactant, glyceryl ester derivative and hair care oily ingredient. The hair cleansing composition represents micro emulsion. A method for preparing the hair cleansing composition consists of the following steps of: mixing the anionic surfactant to water in a first step mixing the glyceryl ester derivative and hair care oily ingredients in an additional container in a second step adding the mixture prepared in the first step to the mixture prepared in the second step and stirring the mixed materials while heating the mixed materials and cooling down the mixed materials.본 발명은 마이크로에멀젼 상을 포함하는 모발 세정제 조성물에 관한 것으로, 보다 상세하게는 세정계면활성제인 1종 이상의 음이온 계면활성제, 특정 비율의 글리세릴 에스터 유도체 및 모발 보호 유성 성분을 함유하여 다량의 유성 효능 성분을 용이하게 미립자화하고, 모발에 대한 적절한 세정 효과와 젖음 시 컨디셔닝 및 점도 형성, 온도에 따른 상 안정성이 양호한 투명 또는 불투명한 상의 세정제 조성물을 제공한다.