The present invention relates to a method of preparing a mosquito repellent composition which is conceptually different from insecticides in that the mosquito repellent composition repels, rather than exterminates, mosquitoes. The composition prevents mosquitoes from approaching and entering by desensitizing their navigational instinct to gather near human habitations to consume blood, and since the repellent effect lasts for long periods of time, pleasant environments free of mosquitoes can be maintained for long periods of time. The method comprises the steps of: (a) preparing and naturally drying 45-55% of Zanthoxylum piperitum barks and 45-55% of Zanthoxylum piperitum leaves (b) adding sulfur powder to water and heating to about 40-50°C to prepare a sulfur water, and while maintaining the sulfur water at about 20-30°C, immersing the Zanthoxylum piperitum barks and leaves therein and aging for 2-7 days (c) preparing, mixing, and naturally drying 20% of each of Pelargonium citrosum vanleenii, Chrysanthemum cinerariaefolium, Eucalyptus globulus, Cinnamomum cassia, and Ocimum basilicum (d) placing the Pelargonium citrosum vanleenii, Chrysanthemum cinerariaefolium, Eucalyptus globulus, Cinnamomum cassia, Ocimum basilicum into water mixed with butylene glycol and heating for 10-30 minutes for a first time and cooling, and then heating again in a water bath at 75-80°C for 4-6 hours for a second time and cooling to produce an extract mixture water and (e) mixing the aged sulfur water with the extract mixture water in the ratio 6 : 4 to produce a complex extract water.COPYRIGHT KIPO 2017본 발명은 직접적으로 모기를 박멸하는 살충의 개념이 아닌 기피 효과를 위한 것으로 모기가 흡혈을 위하여 사람이 머무는 곳으로 접근하려는 본능적인 운동신경을 마비(둔화)시켜서 모기의 진입과 접근을 차단하며, 특히 장기간에 걸쳐 기피 효과를 유지하기 때문에 모기로부터 차단된 쾌적한 환경을 장기간 유지할 수 있게 되는 모기 기피 효과를 갖는 조성물의 제조방법에 관한 것으로, (a) 초피나무의 껍질 45~55%와 이파리 45~55% 비율로 준비하여 자연 건조시키는 단계 (b) 물에 유황 분말을 넣은 후 40~50℃ 정도로 가열하여 유황수를 준비하고, 상기 유황수의 온도를 20~30℃ 정도로 유지시킨 상태에서 초피나무 껍질과 이파리를 담가 2~7일 간 숙성시키는 단계 (c) 구문초,