To provide a W/O emulsion composition that has excellent emulsion stability of a ceramide even when containing, in an aqueous phase, an inorganic acid and an acidic compound such as an organic acid with 6 or less carbon atoms.SOLUTION: A W/O emulsion composition contains following components (A), (B), (C), (D), (E) and (F): (A) a C12-26 glycerol mono fatty acid ester, (B) a C10-22 higher alcohol, (C) ceramide, (D) an anionic surfactant, (E) a nonionic surfactant with an HLB of 8 or more, and (F) at least one selected from an inorganic acid and an organic acid with 6 or less carbon atoms.SELECTED DRAWING: None【課題】水相中に無機酸及び炭素数６以下の有機酸等の酸性化合物を含有していてもセラミド類の乳化安定性に優れるＷ／Ｏ型乳化組成物の提供。【解決手段】次の成分（Ａ）、（Ｂ）、（Ｃ）、（Ｄ）、（Ｅ）及び（Ｆ）：（Ａ）炭素数１２～２６のグリセリンモノ脂肪酸エステル、（Ｂ）炭素数１０～２２の高級アルコール、（Ｃ）セラミド類、（Ｄ）アニオン性界面活性剤、（Ｅ）ＨＬＢ８以上の非イオン性界面活性剤、（Ｆ）無機酸及び炭素数６以下の有機酸から選ばれる１種以上を含有するＷ／Ｏ型乳化組成物。【選択図】なし
