The present invention relates to a composition comprising crystal of flumioxazin which shows a powder X-Ray diffraction pattern having diffraction peaks with 2θ values)(°) shown in Table 1 of the specification, the pattern being obtained by CuKα rays diffraction analysis, and one or more herbicidal compounds selected from the group B-1, B-2, B-3, B-4, B-5, B-6, B-7, B-8, B-9, B-10, B-11 and B-12 described in the specification. According to the present invention, a wide range of weeds can be controlled in a crop field, land under perennial crops, or non-crop land.
