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Process for preparation of propylene copolymer
专利权人:
BOREALIS AG
发明人:
Resconi Luigi,Töltsch Wilfried,Jingbo Wang
申请号:
US201414906627
公开号:
US9701772(B2)
申请日:
2014.07.22
申请国别(地区):
美国
年份:
2017
代理人:
Westerman, Hattori, Daniels & Adrian, LLP
摘要:
A process for the preparation of a propylene copolymer, preferably a heterophasic propylene copolymer, in a multistage polymerisation process in the presence of a single site catalyst, said process comprising: (I) in a slurry polymerisation step, polymerising propylene and optionally at least one C2-10 alpha olefin comonomer; and subsequently (II) in a gas polymerisation step polymerising propylene and optionally at least one C2-10 alpha olefin comonomer, in the presence of catalyst and polymer from step (I); (III) in a second gas polymerisation step, polymerising propylene and at least one C2-10 alpha olefin comonomer in the presence of the catalyst and polymer from step (II); wherein said catalyst comprises (i) a metallocene complex of a group (IV) metal, said metallocene comprising at least two cyclopentadienyl type ligands; (ii) a boron based cocatalyst; and (iii) an aluminoxane cocatalyst; said catalyst being in solid form, preferably in solid particulate form, and being free from an external carrier.
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