The object of the present invention is to provide a honeycomb composite film which contains a film having a honeycomb structure, and a provisional substrate formed on at least one surface of the film having the honeycomb structure such that the provisional substrate is exfoliatable and to provide a method for producing the honeycomb composite film which includes forming an exfoliation layer on a provisional substrate, and forming a film, the forming a film includes casting a solution containing an organic solvent and a high-polymer compound on any one of the exfoliation layer and a substrate, forming droplets in the obtained film, and vaporizing the organic solvent and the droplets to thereby produce a honeycomb-like porous film having holes in the film.
