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Formaldehyde-free stable microcapsules
专利权人:
Firmenich SA
发明人:
BERTHIER, Damien,LEON, Géraldine,PARET, Nicolas,OUALI, Lahoussine
申请号:
ES12777929
公开号:
ES2683315T3
申请日:
2012.10.29
申请国别(地区):
ES
年份:
2018
代理人:
摘要:
A process for the preparation of a covered core microcapsule, said process comprising the steps of: 1) preparing an oligomeric composition comprising the reaction product of, or obtainable by the joint reaction of: a) a polyamine component in form of melamine or a mixture of melamine and at least one C1-4 compound comprising two NH2 functional groups; b) an aldehyde component in the form of a mixture of glyoxal, a C4-6 2,2-dialkoxy-ethanal and optionally a glyoxalate, said mixture having a glyoxal / 2,2-dialkoxy-ethanal C4-6 molar ratio between 1/1 and 10/1; and c) a protic acid catalyst; 2) preparing an oil-in-water dispersion, in which the droplet size is between 1 and 600 μm, and comprising: i) an oil; ii) an aqueous medium; iii) at least one oligomeric composition as obtained in step 1); iv) at least one crosslinker selected from: A) C4-C12 aromatic or aliphatic di- or tri-isocyanates and their biurets, triurets, trimers and trimethylol propane adduct; and / or B) di- or tri-oxirane compounds of the formula A- (oxyran-2-ylmethyl) n in which n means 2 or 3 and A represents a C2-C6 group optionally comprising 2 to 6 nitrogen atoms and / or oxygen; v) optionally a C1-4 compound comprising two NH2 functional groups; 3) heating said dispersion; 4) cooling said dispersion; and 5) optionally drying the final dispersion to obtain the dry coated core microcapsule.Un procedimiento para la preparación de una microcápsula de núcleo cubierta, comprendiendo dicho procedimiento las etapas de: 1) preparar una composición oligomérica que comprende el producto de reacción de, u obtenible por la reacción en conjunto de: a) un componente de poliamina en forma de melamina o de una mezcla de melamina y al menos un compuesto C1-4 que comprende dos grupos funcionales NH2; b) un componente aldehído en forma de una mezcla de glioxal, un 2,2-dialcoxi-etanal C4-6 y opcionalmente un glioxalato, teniendo dicha mezcla una relación molar de glioxal/2,2-dialcoxi-etanal C4-6 comprendida entre 1/
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