A compound comprising Formula I, or a mixture thereof, wherein Y is a bond or C<;SUB>;m<;/SUB>;H<;SUB>;2m-p<;/SUB>;(OA)<;SUB>;p <;/SUB>;wherein m is 0 to 4, and p is 0 or 1, X' is X or H, X is CH<;SUB>;2<;/SUB>;CH<;SUB>;2<;/SUB>;OA, CH(CH<;SUB>;2<;/SUB>;OA)<;SUB>;2<;/SUB>;, C(CH<;SUB>;2<;/SUB>;OA)<;SUB>;3<;/SUB>;, or X and X' combine to form (CH<;SUB>;2<;/SUB>;CH<;SUB>;2<;/SUB>;)<;SUB>;2<;/SUB>;NCH<;SUB>;2<;/SUB>;CH<;SUB>;2<;/SUB>;OA or (CH<;SUB>;2<;/SUB>;CH<;SUB>;2<;/SUB>;)<;SUB>;2<;/SUB>;O, provided that when X and X' combine to form (CH<;SUB>;2<;/SUB>;CH<;SUB>;2<;/SUB>;)<;SUB>;2<;/SUB>;O then Y is CH<;SUB>;2<;/SUB>;CH(OA)CH<;SUB>;2<;/SUB>;, A is CF<;SUB>;2<;/SUB>;CFHO-R<;SUB>;f <;/SUB>;or H, R<;SUB>;f <;/SUB>;is C<;SUB>;n<;/SUB>;F<;SUB>;2n+1 <;/SUB>;wherein n is an integer of 1 to about 6, M is a cation having a charge equal to a, and a is a positive integer equal to 1 or 2, provided that at least one of X, X', or Y contains A equal to CF2CFHO-R<;SUB>;f<;/SUB>;, and its use in lowering surface tension and imparting improved surface effects.