The present invention provides improved processes for preparing chemically and chirally pure Solifenacin base. The present invention also provides for a composition comprising of a salt of Solifenacin having at least 98% purity. The present invention also discloses certain new salts of Solifenacin as well as new polymorphic forms of Solifenacin hydrochloride and Solifenacin oxalate, in pure form.