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Composition polymérisable contenant des initiateurs comprenant plusieurs atomes de Germanium
专利权人:
IVOCLAR VIVADENT AG
发明人:
MOSZNER, NORBERT, PROF. DR.,ZEUNER, FRANK, DR.,LISKA, ROBERT, PROF. DR.,RHEINBERGER, VOLKER, DR.,LAMPARTH, IRIS, DR.,FISCHER, URS-KARL
申请号:
EP08102841.7
公开号:
EP2103297B1
申请日:
2008.03.20
申请国别(地区):
EP
年份:
2012
代理人:
摘要:
Composition (A) comprises at least a polymerizable binder (B) and a polymerization initiator (C) comprising at least an acyl germanium compound (D). Composition (A) comprises at least a polymerizable binder (B) and a polymerization initiator (C) comprising at least an acyl germanium compound (D) of formula ((-R 0>;-(C(=O) m-Ge(R 2>;) p(R 3>;) 3 - n - p-(R 1>;) n-) z) u) (I) or (R 0>;-(C(=O) m-Ge(R 1>;)(R 2>;)(R 3>;)) z) (II), (III), (R 1>;-Ge(R 2>;)(R 3>;)-(Ge(R 2>;)(R 3>;)) w-Ge(R 1>;)(R 2>;)(R 3>;)) (IV), (V) or (VI). Either R 0>;a z-valent aliphatic, aromatic or aliphatic-aromatic 1-50C-hydrocarbon; or R 0>;a bivalent aliphatic, aromatic or aliphatic aromatic 1-50C hydrocarbon; either u : 1; or u : 2-100; z : 2-10; either R 1>;e.g. H; or R 1>;-C(=O)-; R 2>;e.g. H or 1-50C hydrocarbon; either R 3>;1-18C-alkyl or 2-18C-alkenyl (both optionally substituted); or R 3>;2-18C-alkyl or 2-18C-alkylene (both one or more times interrupted and substituted); or R 3>;e.g. 2-18C-alkyl or 2-18-alkylene; or R 3>;e.g. trimethylsilyl or -COOH; or R 3>;e.g. phenyl or naphthyl; and m, n, p : 0 or 1. With conditions. Full Definitions are given in the DEFINITIONS (Full Definitions) Field. Independent claims are included for: (1) a system for the manufacture of molded bodies containing (A) and a light emitting diode light source; and (2) a process for the preparation of a molded body, comprising applying (A) on the body and subsequently completely or partially hardening. [Image].
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