A dendritic polymer and a magnetic resonance imaging contrast agent employing the same. The magnetic resonance contrast agent comprises a polymer according to the structure of or wherein, S is cyclosilane moiety with j silicon oxygen residual groups, and j is not less than 2; P is, and l is not less than 1; D is a C3-30 dendritic moiety having a plurality of oxygen residue; X is a moiety having bi-functional groups; Z is a C3-20 moiety having a plurality of functional group; L is a metal cation; and i is not less than 2.一種樹枝狀高分子及包含其之磁共振顯影造影劑,該樹枝狀高分子包含具有如以下結構之高分子化合物: 或 其中,S係為環矽烷,其具有j個Si-O-殘基;P係為 ,l係為大於或等於1之整數;D係為複個氧殘基(oxygen residue)之C3-30的多分枝基團;X係為具有雙官能基之基團;Z係為具有複數個官能基之C3~20的基團;L係為金屬陽離子;i係為不小於2之整數;以及,j係大於或等於2之整數。