A countercurrent extraction process that involves a plurality of mixing and separation steps for the fractionation of a food material containing phospholipids in two or more fractions enriched in one or more phospholipids, comprising the following steps: i) contacting the starting material containing phospholipids under stirring with an extractant comprising an aliphatic alcohol selected from C1 to C3 alcohols and mixtures thereof for a period of time sufficient to effect the transfer of at least a fraction of the phospholipids to the extractant; ii) separating the mixture obtained in an extract enriched in phospholipids from the residual refining by a process comprising applying centrifugal forces; wherein the phospholipid-enriched extract of each separation stage is at least partly returned to the previous one, or to a subsequent additional mixing stage, where the general process flow is countercurrent which means that the phospholipid-containing material is contacts the extractant of a second or subsequent stage in a first stage, and so on and where a phospholipid enriched final extract is separated from the first residual refining; wherein the final extract comprises at least 25% by weight phosphatidylcholine (PC), and more than 50% by weight insoluble in acetone (AI).Un proceso de extracción a contracorriente que implica una pluralidad de etapas de mezclado y separación para el fraccionamiento de un material alimenticio que contiene fosfolípidos en dos o más fracciones enriquecidas en uno o más fosfolípidos, que comprende las siguientes etapas: i) poner en contacto el material de partida que contiene fosfolípidos bajo agitación con un extractante que comprende un alcohol alifático seleccionado de alcoholes de C1 a C3 y mezclas de los mismos durante un periodo de tiempo suficiente para efectuar la transferencia de al menos una fracción de los fosfolípidos al extractante; ii) separar la mezcla obtenida en un extracto enriquecido en fosfolípidos a partir del refin