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具有尤其是氣味控制與顏色穩定性之改良性質的超吸收劑聚合物及其製造方法
专利权人:
EVONIK INDUSTRIES AG
发明人:
LOICK, CHRISTOPH,洛依克 克里斯多夫,洛依克 克里斯多夫,SMITH, SCOTT,史密斯 史考特,史密斯 史考特
申请号:
TW103107173
公开号:
TW201434926A
申请日:
2014.03.04
申请国别(地区):
TW
年份:
2014
代理人:
摘要:
The present invention relates to a water-absorbing polymer and to a process for preparation, comprising the process steps of (i) mixing (α1) 0.1 to 99.999% by weight, preferably 20 to 98.99% by weight and more preferably 30 to 98.95% by weight of polymerizable, ethylenically unsaturated monomers containing acid groups, or salts thereof, or polymerizable, ethylenically unsaturated monomers including a protonated or quaternized nitrogen, or mixtures thereof, particular preference being given to mixtures including at least one ethylenically unsaturated monomers containing acid groups, preferably acrylic acid, (α2) 0 to 70% by weight, preferably 1 to 60% by weight and more preferably 1 to 40% by weight of polymerized, ethylenically unsaturated monomers copolymerizable with (α1), (α3) 0.001 to 10% by weight, preferably 0.01 to 7% by weight and more preferably 0.05 to 5% by weight of one or more crosslinkers, (α4) 0 to 30% by weight, preferably 1 to 20% by weight and more preferably 5 to 10% by weight of water-soluble polymers, (α5) 0-20% by weight, preferably 2.5-15% by weight and more preferably 5-10% by weight of water, and (α6) 0-20% by weight, preferably 0-10% by weight and more preferably 0.1-8% by weight of one or more assistants, where the sum of the weights of (α1) to (α6) is 100% by weight, (ii) free-radical polymerization with crosslinking to form a water-insoluble, aqueous untreated hydrogel polymer, (iii) drying the hydrogel polymer, (iv) grinding and sieving the water-absorbing polymer to size, (v) surface postcrosslinking the ground and sieved hydrogel polymer and (vi) drying and finishing the water-absorbing polymer, wherein preferably 0.07 to 7% by weight of a salt of an α,β-diunsaturated carboxylic acid, based on the weight of (α1), from the group of α,β-diunsaturated carboxylic acids has been treated with the water-absorbing polymer and 0.00001 to 5% by weight, preferably 0.002 to 4% by weight and more preferably 0.007 to 3.5% by weight of a colour stab
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