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具改良之氣味控制能力的超吸收劑聚合物及其製造方法
专利权人:
EVONIK INDUSTRIES AG
发明人:
LOICK, CHRISTOPH,洛尹克 克里斯多佛,SMITH, SCOTT,史密斯 史考特,洛尹克 克里斯多佛,史密斯 史考特
申请号:
TW104106633
公开号:
TW201534648A
申请日:
2015.03.03
申请国别(地区):
TW
年份:
2015
代理人:
摘要:
The present invention relates to a water-absorbing polymer and to a process for preparation, comprising the process steps of (i) mixing (α1) 0.1 to 99.999% by weight, preferably 20 to 98.99% by weight and more preferably 30 to 98.95% by weight of polymerizable, ethylenically unsaturated monomers containing acid groups, or salts thereof, or polymerizable, ethylenically unsaturated monomers including a protonated or quaternized nitrogen, or mixtures thereof, particular preference being given to mixtures including at least ethylenically unsaturated monomers containing acid groups, preferably acrylic acid, (α2) 0 to 70% by weight, preferably 1 to 60% by weight and more preferably 1 to 40% by weight of polymerized, ethylenically unsaturated monomers copolymerizable with (α1), (α3) 0.001 to 10% by weight, preferably 0.01 to 7% by weight and more preferably 0.05 to 5% by weight of one or more crosslinkers, (α4) 0 to 30% by weight, preferably 1 to 20% by weight and more preferably 5 to 10% by weight of water-soluble polymers, (α5) 0-90% by weight, preferably 2.5-75% by weight and more preferably 10-60% by weight of water, and (α6) 0-20% by weight, preferably 0-10% by weight and more preferably 0.1-8% by weight of one or more additives, where the sum of the weights of (α1) to (α6) is 100% by weight, (ii) free-radical polymerization with crosslinking to form a water-insoluble, aqueous untreated hydrogel polymer, (iii) comminuting the hydrogel polymer, (iv) drying the hydrogel polymer, (v) grinding and sieving the water-absorbing polymer to size, (vi) surface post-crosslinking the ground and sieved hydrogel polymer and (vii) finishing the water-absorbing polymer, wherein the water-absorbing polymer has been treated with 0.0001 to 3% by weight, preferably 0.0002 to 2% by weight and more preferably 0.0007 to 1.8% by weight of a peroxo compound, based on (α1), after the polymerization is treated, and to a process for producing a hydrogel polymer, to the product of the process a
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