process for selective hydrocarbon nitration, process for preparing a nitroalcohol, an aminoalcohol, an oxazolidine, an n-alkylhydroxylamine and a compound, compound, use of an aminoalcohol, an oxazolidine, a hydroxylamine and compound use.
DOW GLOBAL TECHNOLOGIES INC;ANGUS CHEMICAL COMPANY
发明人:
DANIEL M. TRAUTH,GEORGE DAVID GREEN,IAN A. TOMLINSON,RAYMOND SWEDO,RICHARD L. JAMES
申请号：
BRPI0907297
公开号：
BRPI0907297A2
申请日:
2009.04.08
申请国别(地区):
BR
年份:
2016
代理人:
摘要：
A compound selected from the group consisting of formula I-1, II-1, III-1 and IV-1: or a compound selected from the group consisting of: 2-(hydroxylamino)hexane, 3-(hydroxylamino)hexane, 2-(hydroxylamino)octane, and 3-(hydroxylamino)octane, wherein: R 7 and R 9 are independently linear C 2 -C 17 alkyl； R 11 is an unsubstituted linear C 2 -C 17 alkyl； R 8 is H or linear C 1 -C 8 alkyl； R 10 and R 14 are independently H, linear C 1 -C 8 alkyl, or CH 2 OH, or R 9 , R 10 , and the carbon to which they are attached form an eight membered cycloalkyl ring； R 12 is H, an unsubstituted linear C 1 -C 8 alkyl, or CH 2 OH, or R 11 , R 12 , and the carbon to which they are attached form a C 9 -C 11 cycloalkyl ring； R 13 is C 2 -C 20 alkyl, C 3 -C 12 cycloalkyl, aryl, or aryl-alkyl-； R 14 is H or C 1 -C 12 alkyl, or R 13 and R 14 together with the carbon to which they are attached form a C 3 -C 12 cycloalkyl ring； R 15 is H, or R 14 , R 15 , and the atoms to which they are attached form an oxazolidine ring that is optionally substituted with C 1 -C 6 alkyl； and R 16 is H, C 1 -C 12 alkyl, C 3 -C 12 cycloalkyl, or aryl； provided that: when the compound is selected from formula I-1, the total number of carbons in R 7 and R 8 , together with the carbon to which they are attached, is 10 to 18； and the compound is not 1-nitrodecane, 2-nitrodecane, 1-nitroundecane, 2-nitroundecane, 3-nitroundecane, 4-nitroundecane, 5-nitroundecane, 6-nitroundecane, 1-nitrododecane, 2-nitrododecane, 3-nitrododecane, 4-nitrododecane, 5-nitrododecane, 6-nitrododecane, 1-nitrotridecane, 2-nitrotridecane, 3-nitrotridecane, 6-nitrotridecane, 1-nitrotetradecane, 1-nitropentadecane, 1-nitrohexadecane, 2-nitrohexadecane, 1-nitroheptadecane, 1-nitrooctadecane, or 2-nitrooctadecane； when the compound is selected from formula II-1, if R 10 is H or linear C 1 -C 8 alkyl, the total number of carbons in R 9 and R 10 , together with the carbon to which they are attached, is 5 to 18；
