The invention relates to a composition comprising:(i) a trialkylsiloxysilylcarbamoyl pullulan compound,(ii) a polymethyl methacrylate polymer,(iii) a mattifying substance, and(iv) at least one volatile hydrocarbon oil.The invention is also targeted at the use of such a composition for making up and/or caring for keratinous substances, the skin and the lips, and more particularly in mascaras, foundations and lipsticks.