The invention provides a composition comprising a selenite-containing compound and a pharmaceutically acceptable acid selected from the group consisting of citric acid, acetic acid, malic acid, carbonic acid, sulfuric acid, nitric acid, hydrochloric acid, a fruit acid and mixtures thereof; which composition is useful for treating or preventing inflammatory periodontal disease, mycosis, sunburn or an insect bite; or accelerating healing of an inflammatory burn or wound.