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Method for producing water-absorbent resin
专利权人:
Noriko Honda
发明人:
Noriko Honda,Ayaka Watanabe,Kimihiko Kondo
申请号:
US14000150
公开号:
US09221030B2
申请日:
2012.03.12
申请国别(地区):
US
年份:
2015
代理人:
摘要:
A method for producing a water-absorbent resin includes a polymerization step of polymerizing a polymerizable component containing a water-soluble ethylenically unsaturated monomer dissolved in water using a water-soluble azo-type radical polymerization initiator to obtain a reaction system including a water-absorbent resin precursor, and a dehydration step of removing water from the reaction system by heating. In the dehydration step, a water-soluble radical polymerization initiator is added to the reaction system at any first dehydration stage when the residual water rate calculated by the formula (1) is 50% or more, and a reducing substance is added to the reaction system at any second dehydration stage when the residual water rate decreases from that at the first dehydration stage by 10% or more. According to this production method, a water-absorbent resin having satisfactory water-absorption capacity can be produced while suppressing the content of residual monomers.Residual⁢⁢Water⁢⁢Rate⁢⁢(%)=Mass⁢⁢of⁢⁢Water⁢⁢Remainingin⁢⁢Reaction⁢⁢SystemMass⁢⁢of⁢⁢Water⁢-⁢SolubleEthylenically⁢⁢UnsaturatedMonomer⁢⁢Used⁢⁢inPolymerization⁢⁢Step×100(1)
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