The exemplary system and method facilitate excitation of RF magnetic fields in ultra-high field (UHF) magnetic resonance (MRI) systems (e.g., MRI/NMR system) using a slotted waveguide array (SWGA) as an exciter coil. The exemplary exciter coil, in some embodiments, is configurable to provide RF magnetic field B1+ with high field-uniformity, with high efficiency, with excellent circular polarization, with negligible axial z-component, with arbitrary large field of view, and with exceptional possibilities for field-optimizations via RF shimming.