An aqueous ink composition including water; an optional co-solvent; anoptionalcolorant; and a composite comprising a sulfonated polyester matrix having aplurality of silver nanoparticles dispersed within the matrix. A processincludingincorporating the aqueous ink into an ink jet printing apparatus; ejectingdropletsof ink in an imagewise pattern onto an intermediate transfer member ordirectlyonto a final image receiving substrate; optionally, heating the image topartially orcompletely remove solvents; and optionally, when an intermediate transfermember is used, transferring the ink in the imagewise pattern from theintermediate transfer member to a final recording substrate.