Provided is a nanophosphor having a core/double shell structure, the nanophosphor including a upconversion core including a Yb3+, Ho3+, and Ce3+− co-doped fluoride-based nanophosphor represented by Formula 1; a first shell surrounding at least a portion of the upconversion core, and comprising a Nd3+ and Yb3+ co-doped fluoride-based crystalline composition represented by Formula 2; and a second shell surrounding at least a portion of the first shell, and having paramagnetic properties represented by Formula 3.