A photocatalytic structural member is provided with a substrate having a concave-convex structure formed on a surface thereof, and a photocatalyst film which is disposed on a side of the concave-convex structure of the substrate and reflects a shape of the concave-convex structure. The concave-convex structure is formed with a pitch smaller than a wavelength of light which causes a photocatalytic reaction on the photocatalyst film. A deodorizing device is provided with the photocatalytic structural member, a light source which emits the light from a side of the substrate to the photocatalytic structural member, and a fan which causes an air to flow to the photocatalytic structural member.