Liquid formulation compositions and medicament delivery devices, and methods for preparing and using thereof. For example, the liquid formulation composition comprises a solvent and liquid particles, which includes surfactants and is dispersed in the solvent. The volume average particle size of the liquid particles is less than about 100 µm;the surface tension of the liquid formulation composition is less than about 60 mN/m;and the absolute value of zeta potential is greater than about 15 mV. The containment vessel may be a sprayer or a dropping device.