Systems and methods are provided for the free supply of solvent volatile compounds, where it is used as a means of energy source to release volatile compounds.Systems and methods are provided in the present at least one advantage that (1) does not require Solvent (e.g., Water)； (2) the immediate release of volatile compounds (e.g.You can release 1-mcp of HAIP within milliseconds or seconds instead of minutes or Hours of the existing method using Water)； and / or (3) Home Detention and instantaneous supply of Volatile Compound. Try to use for fruits and vegetables, as well as a plant or a part of it.Claim 1: a Solvent Free System for supplying a Volatile Compound, which comprises (a) a molecular complex of Volatile Compound with a molecular Encapsulating agent； (b) a Compartment of treatment； and (c) means of Energy Source. The system of claim 4: According to claim 1, wherein the volatile Compound comprises a ciclopropeno.Claim: the system according to claim 1, wherein the molecular Encapsulating Agent is selected from the group consisting of substituted Cyclodextrins not substituted Cyclodextrins, Crown ethers, Zeolites, and combinations of them.Claim 1: the system according to claim 1, wherein the treatment compartment is selected from the group consisting of a Thermal Desorption Tube, a Glass Bottle, a Tedlar bag and combinations of them.Se proporcionan sistemas y métodos para el suministro libre de solventes de compuestos volátiles, donde se usa un medio de fuente de energía para liberar los compuestos volátiles. Los sistemas y métodos proporcionados en la presente tienen al menos una ventaja de que (1) no se requiere solvente (por ejemplo, agua)； (2) liberación inmediata de compuestos volátiles (por ejemplo, se puede liberar 1-MCP de HAIP en un lapso de milisegundos o segundos en lugar de minutos u horas del método existente usando agua)； y/o (3) inicio y detención instantánea del suministro del compuesto volátil. Para usar para tratar frutas y vegetales, como
