A graphene thermostatic fabric includes a fibrous tissue and a graphene thermostatic layer. The fibrous tissue has a first tissue surface, a second tissue surface and interspace between the first tissue surface and the second tissue surface. The graphene thermostatic layer adheres to the first tissue surface, fills a part of the interspace, and includes at least a hydrophobic resin and nano graphene sheets dispersed in the hydrophobic resin. A thermal conductivity of the graphene thermostatic layer varies with ambient temperature, and the thermal conductivity of the graphene thermostatic layer perpendicular to the first tissue surface is less than the thermal conductivity of the graphene thermostatic layer parallel to the first tissue surface.一種石墨烯恆溫織物,包含:纖維組織以及石墨烯恆溫層。纖維組織具有第一組織面、第二組織面及位於第一組織面與第二組織面之間的空隙。石墨烯恆溫層附著於第一組織面且填入部分之空隙,包含:至少一疏水性樹脂及分散於疏水性樹脂之奈米石墨烯片,其中石墨烯恆溫層之熱傳導值隨環境溫度的變化而變化,且石墨烯恆溫層垂直於第一組織面之熱傳導值小於石墨烯恆溫層平行於第一組織面之熱傳導值。